Advertisement

Thioboration of phenylacetonitrile in order to synthesize chelated boron compounds

  • V. A. Dorokhov
  • O. G. Boldyreva
Organic Chemistry
  • 28 Downloads

Conclusions

  1. 1.

    Alkylthiodiorganoboranes add at the C=N bond of phenylacetonitrile under mild conditions to form diorganoboryl derivatives of the respective S-alkylthioimidates.

     
  2. 2.

    By means of the reaction of phenylacetonitrile with alkylthiodiorganoboranes (in 2∶1 ratio), chelate compounds of boron were synthesized with the respective deprotonated β-iminothioimidates as ligands.

     

Keywords

Boron Mild Condition Boron Compound Chelate Compound Phenylacetonitrile 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    B. M. Mikhailov, V. A. Dorokhov, and I. P. Yakovlev, Izv. Akad. Nauk SSSR, Ser. Khim., 332 (1966).Google Scholar
  2. 2.
    T. Mukaijama, K. Inomata, and S. Yamamoto, Tetrahedron Lett., 1097 (1971).Google Scholar
  3. 3.
    T. Mukaijama, S. Yamamoto, and K. Inomata, Bull. Chem. Soc. Jpn.,44, 2807 (1971).Google Scholar
  4. 4.
    V. A. Dorokhov and M. F. Lappert, J. Chem. Soc., 433 (1969).Google Scholar
  5. 5.
    L. Bellamy, in: New Data on the Infrared Spectra of Complex Molecules [Russian translation], Mir, Moscow (1971), p. 83.Google Scholar
  6. 6.
    V. A. Dorokhov and B. M. Mikhailov, Dokl. Akad. Nauk SSSR,187, y1300 (1969).Google Scholar
  7. 7.
    V. A. Dorokhov, O. G. Boldyreva, B. M. Zolotarev, O. S. Chizhov, and B. M. Mikhailov, Izv. Akad. Nauk SSSR, Ser. Khim., 1843 (1977).Google Scholar
  8. 8.
    B. M. Mikhailov, G. S. Ter-Sarkisyan, and N. N. Govorov, Izv. Akad. Nauk SSSR, Ser. Khim., 2756 (1976).Google Scholar
  9. 9.
    V. A. Dorokhov, B. M. Zolotarev, O. S. Chizhov, and B. M. Mikhailov, Izv. Akad. Nauk SSSR, Ser. Khim., 1587 (1977).Google Scholar

Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • V. A. Dorokhov
    • 1
  • O. G. Boldyreva
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

Personalised recommendations