EPR determination of the rate constants of detachment of hydrogen from triethylsilane by metal carbonyl radicals

  • R. G. Gasanov
  • S. Kh. Dotdaev
Physical Chemistry

Conclusions

The rate constants of detachment of hydrogen from triethylsilane by radicals of rhenium and manganese pentacarbonyls, tungsten cyclopentadienyltricarbonyl, and iron eyclopentadienyldicarbonyl were determined, and the order of the reactivity of the metal carbonyls was hypothesized.

Keywords

Hydrogen Iron Manganese Tungsten Carbonyl 

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Literature cited

  1. 1.
    R. G. Gasanov, E. G. Sadykhov, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 1031 (1986).Google Scholar
  2. 2.
    R. G. Gasanov, S. Kh. Dotdaev, and V. N. Khandozhko, Izv. Akad. Nauk SSSR, Ser. Khim., 2186 (1985).Google Scholar
  3. 3.
    C. Chatgilialogly, J. C. Scaiano, and K. U. Ingold, Organometal.,1, 466 (1982).Google Scholar
  4. 4.
    R. G. Gasanov, L. V. Ivanova, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 938 (1984).Google Scholar
  5. 5.
    K. U. Ingold, J. Lusztyk, and J. C. Scaiano, J. Am, Chem. Soc.,106, 343 (1984).Google Scholar
  6. 6.
    R. G. Gasanov and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 1244 (1981).Google Scholar
  7. 7.
    J. A. Pople, W. G. Schneider, and H. J. Bernstein, High-Resolution Nuclear Magnetic Resonance Spectra [Russian translation], Inostr. Lit. Moscow (1962), p. 569.Google Scholar
  8. 8.
    R. G. Gasanov and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 2631 (1984).Google Scholar
  9. 9.
    C. Chatgilialogly, K. U. Ingold, and J. C. Scaiano, J. Am. Chem. Soc.,105, 3292 (1983).Google Scholar
  10. 10.
    H. Chandra, I. M. Davidson, and M. C. R. Symons, J. Chem. Soc. Perkin Trans.,2, 1353 (1982).Google Scholar
  11. 11.
    R. M. Laine and P. C. Ford, Inorg. Chem.,16, 388 (1977).Google Scholar
  12. 12.
    C. Chatgilialogly and K. U. Ingold, J. Am. Chem. Soc.,104, 5123 (1982).Google Scholar

Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • R. G. Gasanov
    • 1
  • S. Kh. Dotdaev
    • 1
  1. 1.A. N. Nesraeyanov Institute of Organoelemental CompoundsAcademy of Sciences of the USSRMoscow

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