Mechanism of the catalytic action of penta(dimethylsulfoxido)vanadyl hexathiocyanatoplatinate in the liquid-phase oxidation of cyclohexene
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The complex studied — penta (dimethylsulfoxido) vanadyl hexathiocyanatoplatinate (I) is an effective catalyst for the low-temperature oxidation of cyclohexene in alcoholic media, ensuring a high reaction rate up to a high degree of conversion.
It has been established that there is a synergism between the component parts of the catalyst, the maximum rate of oxidation of cyclohexene being observed with V/Pt=2.
In the initial stages of the oxidation of cyclohexene in the presence of (I), the reaction rate is described by the kinetics of a chain growth-chain breaking process.
KeywordsOxidation Cyclohexene Penta Maximum Rate Catalytic Action
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