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Mechanism of the catalytic action of penta(dimethylsulfoxido)vanadyl hexathiocyanatoplatinate in the liquid-phase oxidation of cyclohexene

  • S. N. Kholuiskaya
  • V. V. Kasparov
  • V. V. Kovalev
  • A. A. Konovalova
  • V. L. Rubailo
Physical Chemistry

Conclusions

  1. 1.

    The complex studied — penta (dimethylsulfoxido) vanadyl hexathiocyanatoplatinate (I) is an effective catalyst for the low-temperature oxidation of cyclohexene in alcoholic media, ensuring a high reaction rate up to a high degree of conversion.

     
  2. 2.

    It has been established that there is a synergism between the component parts of the catalyst, the maximum rate of oxidation of cyclohexene being observed with V/Pt=2.

     
  3. 3.

    In the initial stages of the oxidation of cyclohexene in the presence of (I), the reaction rate is described by the kinetics of a chain growth-chain breaking process.

     

Keywords

Oxidation Cyclohexene Penta Maximum Rate Catalytic Action 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    I. P. Skibida and P. Kok, Izv. Akad. Nauk SSSR, Ser. Khim., 2691 (1974).Google Scholar

Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • S. N. Kholuiskaya
    • 1
  • V. V. Kasparov
    • 1
  • V. V. Kovalev
    • 1
  • A. A. Konovalova
    • 1
  • V. L. Rubailo
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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