Skip to main content
SpringerLink
Log in

Reaction of unsymmetrical fluorinated β-diketones with dihalophosphoranes: The synthesis of α,β-ynones

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Unsymmetrical polyfluorinated β-diketones react with dihalophosphoranes to form mixtures of regioisomeric fluorinated α,β-ynones.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. H. Hoffmann and H. J. Diehr, Tetrahedron Lett., 583 (1962).

  2. H. J. Harwood and K. A. Pollart, J. Org. Chem.,28, 3430 (1963).

    Google Scholar 

  3. V. I. Saloutin, K. I. Pashkevich, and I. Ya. Postovskii, Zh. Vses. Khim. Obshch. im. D. I. Mendeleeva, No. 2, 238 (1976).

    Google Scholar 

  4. K. I. Pashkevich, V. I. Filyakova, and I. Ya. Postovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2346 (1981).

  5. V. W. Armstrong, N. H. Chishti, and R. Ramage, Tetrahedron Lett., 375 (1975).

  6. Y. Shen, Y. Xin, W. Cen, and J. Huang, Synthesis, 35 (1984).

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Urals Branch, Academy of Sciences of the USSR, Sverdlovsk

    P. I. Chechulin, V. I. Filyakova & K. I. Pashkevich

Authors
  1. P. I. Chechulin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. I. Filyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. I. Pashkevich
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 203–204, January, 1989.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chechulin, P.I., Filyakova, V.I. & Pashkevich, K.I. Reaction of unsymmetrical fluorinated β-diketones with dihalophosphoranes: The synthesis of α,β-ynones. Russ Chem Bull 38, 189–190 (1989). https://doi.org/10.1007/BF00953736

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00953736

Search

Navigation