Electron phototransfer through the membranes of lipid vesicles containing an osmium trisdipyridyl complex

  • E. I. Knerel'man
  • N. K. Khannanov
  • V. Ya. Shafirovich
  • E. E. Yablonskaya
Brief Communications

Conclusions

  1. 1.

    Measurements were carried out for the rates of the individual steps of electron phototransfer in a vesicular system with Os(bpy)32+ in the inner layer, (bpy)2Os[bpy(C17)2]2+ in the bilayer, and Ru(bpy)33+ in the external solution.

     

Temperature does not have a significant effect on the rate of electron transfer from (bpy)2Os[bpy(C17)2]2+ localized in the internal monolayer to (bpy)2Os[bpy(C17)2]3+ in the external monolayer.

Keywords

Lipid Electron Transfer Osmium External Solution Lipid Vesicle 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    E. I. Knerel'man and V. Ya. Shafirovich, Izv. Akad. Nauk SSSR, Ser. Khim., 2213 (1986).Google Scholar
  2. 2.
    J. L. Braddock and T. J. Meyer, J. Am. Chem. Soc.,95, 3158 (1973).Google Scholar
  3. 3.
    Gmelins Handbuch der Anorganischen Chemie, Kobalt. GMBH, Verlag Chemie, Vol. 58 (1964), p. 426.Google Scholar
  4. 4.
    K. D. Bos, J. G. Kraaijkamp, and J. G. Noltes, Synth. Commun.,9, 497 (1979).Google Scholar
  5. 5.
    O. Johansen, C. Kowala, A. W-H. Mau, and W. H-F. Sasse, Austral. J. Chem.,32, 1453 (1979).Google Scholar
  6. 6.
    E. E. Yablonskaya and V. Ya. Shafirovich, Nouv. J. Chim.,8, 117 (1984).Google Scholar
  7. 7.
    A. Chrzeczczyk, A. Wishnia, and C. S. Springer, Biochim. Biophys. Acta,470, 161 (1977).PubMedGoogle Scholar
  8. 8.
    W. E. Ford, J. W. Otvos, and M. Calvin, Proc. Nat. Acad. Soc. USA (1979).Google Scholar
  9. 9.
    N. K. Khannanov, V. A. Kuz'min, P. P. Levin, et al., Khim. Fiz.,5, 1358 (1986).Google Scholar
  10. 10.
    V. J. Holzwarth and H. Jürgensen, Ber. Bunsenges. Phys. Chem.,78, 526 (1974).Google Scholar
  11. 11.
    L. Y.-C. Lee and J. K. Hurst, J. Am. Chem. Soc.,106, 7411 (1984).Google Scholar

Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • E. I. Knerel'man
    • 1
  • N. K. Khannanov
    • 1
  • V. Ya. Shafirovich
    • 1
  • E. E. Yablonskaya
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSR, Chernogolovka BranchUSSR

Personalised recommendations