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Formation of long-lived radicals in addition reactions to perfluoro-4-methyl-2-pentene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The photolysis of liquid solutions of CF3I and (CF3)2CFI in perfluoro-4-methyl-2-pentene at γ 240 run gives longlived radicals, which were identified as radical-adducts formed by the addition of CF3 and (CF3)2CF radicals to the double bond of the perfluorolefin.

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Literature cited

  1. S. R. Allayarov, I. M. Barkalov, V. I. Gol'danskii, and D. P. Kiryukhin, Izv. Akad. Nauk SSSR, Ser. Khim., No. 6, 1225 (1983).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    S. R. Allayarov, D. A. Gordon, I. V. Sumina, I. M. Barkalov & A. I. Mikhailov

Authors
  1. S. R. Allayarov
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  2. D. A. Gordon
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  3. I. V. Sumina
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  4. I. M. Barkalov
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  5. A. I. Mikhailov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 184–185, January, 1989.

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Allayarov, S.R., Gordon, D.A., Sumina, I.V. et al. Formation of long-lived radicals in addition reactions to perfluoro-4-methyl-2-pentene. Russ Chem Bull 38, 170–171 (1989). https://doi.org/10.1007/BF00953727

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  • DOI: https://doi.org/10.1007/BF00953727

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