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An electrochemical variant of the horner reaction

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Cleavage of the activated C-H bond with the formation of a carbonion occurs in the electrolysis of α-substituted phosphonates on platinum or vitreous carbon cathodes. The reaction of the carbanion with carbonyl compounds leads to satisfactory yields of olefins.

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Literature cited

  1. P. E. Iversen and H. Lund, Tetrahedron Lett., 3523 (1969).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    M. E. Niyazymbetov, V. A. Petrosyan, I. Keitel, B. Costisella & K. H. Schwartz

  2. Central Institute of Organic Chemistry, Academy of Sciences of the German Democratic Republic, Berlin

    M. E. Niyazymbetov, V. A. Petrosyan, I. Keitel, B. Costisella & K. H. Schwartz

Authors
  1. M. E. Niyazymbetov
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  2. V. A. Petrosyan
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  3. I. Keitel
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  4. B. Costisella
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  5. K. H. Schwartz
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 172–174, January, 1989.

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Niyazymbetov, M.E., Petrosyan, V.A., Keitel, I. et al. An electrochemical variant of the horner reaction. Russ Chem Bull 38, 159–160 (1989). https://doi.org/10.1007/BF00953722

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  • DOI: https://doi.org/10.1007/BF00953722

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