Ortho-phosphorylated phenols and their methoxymethyl ethers, phosphines, and phosphine oxides

  • E. N. Tsvetkov
  • V. Kh. Syundyukova
  • V. E. Baulin
Organic Chemistry


  1. 1.

    By reaction of o-methoxymethoxyphenyllithium with P(III) acid chlorides and with phosphinyl chlorides o-methoxymethoxyphenylphosphines and methoxymethyl ethers of o-phosphinyl-substituted phenols were obtained, and by hydrolysis transformed into the corresponding o-phosphinyl-substituted phenols.

  2. 2.

    A method for obtaining phenol methoxymethyl ethers was developed by alkylation of phenols with monochlorodimethyl ether in two steps.



Oxide Ether Chloride Hydrolysis Phenol 
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Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • E. N. Tsvetkov
    • 1
  • V. Kh. Syundyukova
    • 1
  • V. E. Baulin
    • 1
  1. 1.Institute of Physiologically Active SubstancesAcademy of Sciences of the USSRChernogolovka

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