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Cleavage of perfluorinated tertiary amines by antimony pentafluoride

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Perfluorinated tertiary amines with a variety of structures undergo dealkylation on heating with SbF5 with the formation of the corresponding azomethines.

  2. 2.

    Amines containing the N-CF3 grouping are cleaved under milder conditions.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. A. Petrov, V. K. Kunanets, B. A. Kvasov, M. V. Galakhov, K. N. Makarov & L. S. German

Authors
  1. V. A. Petrov
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  2. V. K. Kunanets
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  3. B. A. Kvasov
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  4. M. V. Galakhov
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  5. K. N. Makarov
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  6. L. S. German
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 122–126, January, 1989.

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Petrov, V.A., Kunanets, V.K., Kvasov, B.A. et al. Cleavage of perfluorinated tertiary amines by antimony pentafluoride. Russ Chem Bull 38, 110–113 (1989). https://doi.org/10.1007/BF00953712

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  • DOI: https://doi.org/10.1007/BF00953712

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