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Relative kinetics of the radical telomerization of vinyl chloride with carbon tetrabromide and dichlorodibromomethane

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Based on data obtained concerning the relative, kinetics of telomerization of vinyl chloride with CX2Br2 (X=Br, Cl), the radicals CBr3CH2CHCl and CCl22BrCH2ĊHCl are approximately an order of magnitude more reactive (faster) at chain transfer to an electrophilic telogen CX2Br2 compared to addition to vinyl chloride.

  2. 2.

    Tetrabromomethane is more reactive toward chain transfer with respect to telomerization with vinyl chloride than is dichlorodibromomethane.

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Literature cited

  1. B. A. Énglin, T. A. Onishchenko, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 2678 (1971).

  2. L. V. Gurvich, G. V. Karachevtsev, V. N. Kondrat'ev, et al., Chemical Bond Cleavage Energies. Ionization Potentials and Electron Affinities [in Russian], Nauka, Moscow (1974), pp. 89–91.

    Google Scholar 

  3. T. Asahara and M. C. Chou, Bull. Chem. Soc., Jpn.,42, 1373 (1969).

    Google Scholar 

  4. T. T. Vasil'eva, V. A. Kochetkova, B. V. Nelyubin, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 808 (1987).

  5. F. R. Mayo, J. Am. Chem. Soc.,70, 3689 (1948).

    Google Scholar 

  6. R. Kh. Freidlina, T. T. Vasil'eva, G. A. Trapeznikova, and B. V. Nelyubin, Dokl. Akad. Nauk SSSR,247, 1429 (1979).

    Google Scholar 

  7. V. I. Dostovalova, F. K. Velischko, T. T. Vasileva, et al., Org. Magn. Reson.,16, 251 (1981).

    Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR, Moscow

    T. T. Vasil'eva, V. A. Koche-tkova, V. I. Dostovalova & B. V. Nelyubin

Authors
  1. T. T. Vasil'eva
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  2. V. A. Koche-tkova
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  3. V. I. Dostovalova
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  4. B. V. Nelyubin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 109–113, January, 1989.

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Vasil'eva, T.T., Koche-tkova, V.A., Dostovalova, V.I. et al. Relative kinetics of the radical telomerization of vinyl chloride with carbon tetrabromide and dichlorodibromomethane. Russ Chem Bull 38, 97–101 (1989). https://doi.org/10.1007/BF00953709

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  • DOI: https://doi.org/10.1007/BF00953709

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