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Oxidative δ-chlorination of aliphatic alcohols in the system lead tetraacetate-metal chloride

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the oxidation of primary, secondary, and tertiary aliphatic alcohols with the system Pb(OAc)4-metal chloride, the principal product is the δ-chloroalkanol.

  2. 2.

    EPR using spin traps has been used to identify the alkoxyl and secondary C-centered radicals generated in the oxidation.of an alcohol with Pb (OAc)4 and with the system Pb(OAc)4-LiCl.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    N. I. Kapustina, A. V. Lisitsyn & G. I. Nikishin

Authors
  1. N. I. Kapustina
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  2. A. V. Lisitsyn
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  3. G. I. Nikishin
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Additional information

For previous communication, see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 98–105, January, 1989.

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Kapustina, N.I., Lisitsyn, A.V. & Nikishin, G.I. Oxidative δ-chlorination of aliphatic alcohols in the system lead tetraacetate-metal chloride. Russ Chem Bull 38, 86–92 (1989). https://doi.org/10.1007/BF00953706

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  • DOI: https://doi.org/10.1007/BF00953706

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