Conclusions
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1.
A specific geminal interaction in the OCCl triad, which is weakened in comparison to the corresponding ethers, appears in the mono-α-chloro esters RCOOCClR1R2.
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2.
All the mono-α-chloro esters exist in a synclinal conformation with respect to the O-Csp3 bond with a ClCOC(O) dihedral angle equal to 70–90°.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 69–73, January, 1989.
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Bredikhin, A.A., Kirillovich, V.A., Andreeva, A.I. et al. Polarity, polarizability, and structure of esters. Russ Chem Bull 38, 58–63 (1989). https://doi.org/10.1007/BF00953700
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DOI: https://doi.org/10.1007/BF00953700