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EPR study of the complexes of polyhydroxyphenylbenzoxazoletere-phthalamide with VO2+ ions

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It was established by the EPR method that VO2+ ions interact with films based on polyhydroxyphenylbenzoxazoleterephthalamide (PBO) and only form complexes with two units L of the polymer, where the fraction of the PBO units which form VOL2 complexes does not exceed 10%.

  2. 2.

    During the thermooxidation of VO(PBO) films the VO2+ complexes present in them can act as inhibitors and initiators of radical reactions.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    A. I. Kokorin, V. N. Kolot & I. I. Khairullin

Authors
  1. A. I. Kokorin
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  2. V. N. Kolot
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  3. I. I. Khairullin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 56–60, January, 1989.

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Kokorin, A.I., Kolot, V.N. & Khairullin, I.I. EPR study of the complexes of polyhydroxyphenylbenzoxazoletere-phthalamide with VO2+ ions. Russ Chem Bull 38, 45–49 (1989). https://doi.org/10.1007/BF00953697

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  • DOI: https://doi.org/10.1007/BF00953697

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