Conclusions
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1.
The dissociative ionization of spin-coupled bis-chelates of Ni(II) and Pd(II) with derivatives of 1,2-hydroxylaminoxime differs very little from the behavior of coordination compounds with ligands of the nonradical type.
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2.
The difference in the fragmentation of Ni(II) and Pd(II) complexes is due to the greater ability of palladium to form ions containing a π bond and also its smaller affinity toward oxygen.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 53–55, January, 1989.
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Indrichan, K.M., Gérbéléu, N.V. & Larionov, S.V. Mass spectrometric investigation of the coordination compounds of nickel(II) and palladium(II) by using their 1,2-hydroxylamineoxime derivatives. Russ Chem Bull 38, 43–45 (1989). https://doi.org/10.1007/BF00953696
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DOI: https://doi.org/10.1007/BF00953696