Geometric factor in prototropic reactions of neutral and charged radicals

  • K. B. Petrushenko
  • A. I. Vokin
  • V. K. Turchaninov
Physical Chemistry


The difference between the rate constants of thermodynamically favorable proton-transfer reactions between NH- and OH-containing radicals and heterocyclic bases and those diffusion-controlled reactions is due to the reactivity anisotropy of the reagents.


Anisotropy Geometric Factor Charged Radical Heterocyclic Basis Reactivity Anisotropy 
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Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • K. B. Petrushenko
    • 1
  • A. I. Vokin
    • 1
  • V. K. Turchaninov
    • 1
  1. 1.Irkutsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRUSSR

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