Skip to main content
SpringerLink
Log in

Conversion of n-dodecane in the presence of oxygen on an aluminum-vanadium catalyst

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the presence of an aluminum-vanadium catalyst, the formation of n-dodecenes from n-dodecane proceeds via dehydrogenation and oxidative dehydrogenation reactions, and the formation of C6–11 olefins proceeds by the oxidative cracking reaction of hydrocarbons.

  2. 2.

    Under optimum conditions, a 15% yield of C6–12 olefins, including ∼10% of n-dodecenes, is achieved with a 70% selectivity. C6–11 hydrocarbons contain about equal amounts of paraffins and olefins; among them C7–9 hydrocarbons are formed in the highest proportion.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. N. R. Bursian, S. B. Kogan, V. Sh. Gruver, and P. N. Borutskii, Promoted Platinum Catalysts in the Isomerization and Dehydration Process of Paraffin Hydrocarbons [in Russian], Central Sci. Res. Inst. Tech. Inf. Econom. Petrochem., Moscow (1981), p. 44.

    Google Scholar 

  2. V. K. Skarchenko, Dehydrogenation of Hydrocarbons [in Russian], Naukova Dumka, Kiev (1981), p. 199.

    Google Scholar 

  3. G. A. Tarasova and S. G. Roitberg, Izv. Akad. Nauk SSSR, Ser. Khim., 955 (1974).

  4. G. V. Isagulyants, O. D. Sterligov, S. V. Adel'son, and L. V. Fed'ko, Neftekhimiya,23, 331 (1983).

    Google Scholar 

  5. S. V. Adel'son, N. I. Rybakova, E. Yu. Mironova, et al., Neftekhimiya,27, 57 (1987).

    Google Scholar 

  6. Hu Shengen, US Patent No. 3,562,797 (1971); RZhKhim., 24R.641P (1971).

  7. I. P. Belomestnykh, G. V. Shakhnovich, N. N. Rozhdestvenskaya, and G. V. Isagulyants, Izv. Akad. Nauk SSSR, Ser. Khim., 981 (1987).

  8. A. L. Klyachko-Gurvich, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1884 (1961).

  9. V. Ya. Shtern, Gas Phase Oxidation Mechanism of Hydrocarbons [in Russian], Acad. Sci. USSR, Moscow (1960), pp. 326, 336.

    Google Scholar 

  10. A. F. Platé and G. A. Tarasova, Zh. Obshch. Khim.,22, 765 (1952).

    Google Scholar 

  11. W. Bytyn and M. Baerns, Appl. Catal.,28, 199 (1986).

    Google Scholar 

  12. P. Zhou and B. L. Crynes, Ind. Eng. Chem. Proc. Des. Dev.,25, 508 (1986).

    Google Scholar 

  13. J. A. Martens, J. Perez-Parien, and P. A. Jacols, Proc. Int. Symp. Zeolite Catal., Siòfok. Szeged, 487 (1985).

  14. R. Z. Magaril, Mechanism and Kinetics of Homogeneous Thermal Transformations of Hydrocarbons [in Russian], Khimiya, Moscow (1970), pp. 14–16.

    Google Scholar 

  15. A. D. Stepukhovich and V. A. Uglitskii, Kinetics and Thermodynamics of Radical Cracking Reactions [in Russian], Khimiya, Moscow (1975), p. 180.

    Google Scholar 

  16. A. D. Stepukhovich and A. V. Gorokhovskii, Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.,29, 27 (1986).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    O. D. Sterligov, N. I. Rybakova, S. V. Adel'son & G. V. Isagulyants

  2. I. M. Gubkin Moscow Institute of Petroleum and Gas, USSR

    O. D. Sterligov, N. I. Rybakova, S. V. Adel'son & G. V. Isagulyants

Authors
  1. O. D. Sterligov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. I. Rybakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. V. Adel'son
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. V. Isagulyants
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 16–20, January, 1989.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sterligov, O.D., Rybakova, N.I., Adel'son, S.V. et al. Conversion of n-dodecane in the presence of oxygen on an aluminum-vanadium catalyst. Russ Chem Bull 38, 9–12 (1989). https://doi.org/10.1007/BF00953689

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00953689

Keywords

Search

Navigation