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Experimental and molecular statistical study of adsorption of halogenated derivatives of benzene on graphitized thermal black

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    As for chlorobenzenes, in the case of bromobenzenes the values of k1 can only be described with one potential ϕ C... Br for bromobenzenes containing no Br atoms in the ortho position if the molecules of the bromobenzenes are considered planar.

  2. 2.

    The best agreement of the experimental and calculated values of K1 for ortho-substituted chloro- and bromobenzenes can be obtained with combined consideration of the effects of a change in the polarizability and deviation of the ortho-positioned chlorine and bromine atoms from the plane of the benzene ring.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow

    A. K. Buryak & D. P. Poshkus

  2. Institute of Chemistry and Chemical Technology, Academy of Sciences of the Lithuanian SSR, Vilnius

    A. K. Buryak & D. P. Poshkus

Authors
  1. A. K. Buryak
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  2. D. P. Poshkus
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 12–16, January, 1989.

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Buryak, A.K., Poshkus, D.P. Experimental and molecular statistical study of adsorption of halogenated derivatives of benzene on graphitized thermal black. Russ Chem Bull 38, 5–9 (1989). https://doi.org/10.1007/BF00953688

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  • DOI: https://doi.org/10.1007/BF00953688

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