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Formation of perfluoro-1,1,3-trimethylindane in the reaction of trimethylsilylpentafluorobenzene with perfluoro-4-methyl-2-pentene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reaction of pentafluorophenyltrimethylsilane with perfluoro-2-methyl-2-pentene in the presence of cesium fluoride gives perfluoro-1,1,3-trimethylindane in addition to the product of the pentafluorophenylation.

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Literature cited

  1. G. G. Yakobson, T. D. Petrova, and L. S. Kobrina, Fluorine Chemistry Reviews, Vol. 7, Marcel Dekker, New York (1974), p. 115.

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  3. V. V. Bardin, G. G. Furin, and I. V. Stennikova, Second Soviet-West German Symposium on Fluorine Chemistry, Novosibirsk (1988), p. 37.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 477–479, February, 1989.

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Bardin, V.V., Petrov, V.A., Stennikova, I.V. et al. Formation of perfluoro-1,1,3-trimethylindane in the reaction of trimethylsilylpentafluorobenzene with perfluoro-4-methyl-2-pentene. Russ Chem Bull 38, 420–421 (1989). https://doi.org/10.1007/BF00953645

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  • DOI: https://doi.org/10.1007/BF00953645

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