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Complexes of manganese borohydride with the borohydrides of organic cations

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Reaction of MnCBH4)2(THF)3 with tetrabutylammoniura and tetraphenylphosphonium borohydndes, and with tetraphenylphosphonium chloride, has given the compounds (Bu4N)[Mn(BH4)3], (Ph4P)[Mn(BH4)3], (Ph4P)[Mn(BH4)3(THF)], (Ph4P) [Mn(BH4)3Cl], and (Ph4P) [Mn(BH4)2Cl(THF)], which have been characterized by IR spectroscopy and thermogravimetric studies.

  2. 2.

    The crystal and molecular structure of the manganese complex (Ph4P) [Mn(BH4)3−xClx (THF)] (x∼ 0.5) has been found.

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Literature cited

  1. A. P. Borisov, V. D. Makhaev, É. B. Lobkovskii, and K. N. Semenenko, Zh. Neorg. Khim.,31, 86 (1986).

    Google Scholar 

  2. V. D. Makhaev, A. P. Borisov, T. P. Gnilomedova, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1712 (1987).

  3. V. D. Makhaev, A. P. Borisov, T. P. Karpova, et al., Abstracts of Reports of Sixteenth Chugaev All-Union on the Chemistry of Complexes [in Russian], Krasnoyarsk (1987), Part 2, p. 453.

  4. N. N. Mal'tseva and V. S. Khain, Sodium Borohydride [in Russian], Nauka, Moscow (1985), p. 9.

    Google Scholar 

  5. B. Horvath, R. Moseler, and E. G. Horvath, Z. Anorg. Allg. Chem.,450, 165 (1979).

    Google Scholar 

  6. L. V. Titov, L. A. Gavrilova, E. R. Eremin, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1354 (1971).

  7. H. G. Heal, J. Inorg. Nucl. Chem.,16, 208 (1961).

    Google Scholar 

  8. A. P. Borisov, V. D. Makhaev, É. V. Lobkovskii, and K. N. Semenenko, Abstracts of Reports of 5th All-Union Conference on the Chemistry of Nonaqueous Solutions of Inorganic Compounds and Complexes [in Russian], Rostov-on-Don, 87 (1985).

  9. L. V. Titov, L. A. Gavrilova, U. Mirsaidov, et al., Zh. Neorg. Khim.,27, 1953 (1982).

    Google Scholar 

  10. M. Eheman and H. Noth, Z. Anorg. Allg. Chem.,386, 87 (1981).

    Google Scholar 

  11. É. B. Lobkovskii, S. E. Kravchenko, and O. V. Kravchenko, Zh. Strukt. Khim.,23, 111 (1982).

    Google Scholar 

  12. N. Edelstein, Inorg. Chem.,20, 297 (1981).

    Google Scholar 

  13. W. L. Driessen and M. Heijer, Inorg. Chim. Acta,23, 261 (1979).

    Google Scholar 

  14. N. S. Akhmetov, Inorganic Chemistry [in Russian], 2nd edn., Vysshaya Shkola, Moscow (1975), p. 329.

    Google Scholar 

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Authors and Affiliations

  1. Institute for Novel Chemical Topics, Academy of Sciences of the USSR, Chernogolovka

    V. D. Makhaev, A. P. Borisov, T. P. Karpova, É. B. Lobkovskii, B. P. Tarasov & A. N. Chekhlov

Authors
  1. V. D. Makhaev
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  2. A. P. Borisov
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  3. T. P. Karpova
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  4. É. B. Lobkovskii
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  5. B. P. Tarasov
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  6. A. N. Chekhlov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 432–438, February, 1989.

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Makhaev, V.D., Borisov, A.P., Karpova, T.P. et al. Complexes of manganese borohydride with the borohydrides of organic cations. Russ Chem Bull 38, 377–382 (1989). https://doi.org/10.1007/BF00953633

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  • DOI: https://doi.org/10.1007/BF00953633

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