Synthesis of 1-substituted 1-vinylcycloalkanes by allylboration of carbonyl compounds and ethoxyacetylene with diorganylborylethylidenecyclopentane and a diorganylborylethylidenecyclohexane

  • Yu. N. Bubnov
  • V. I. Zheludeva
  • A. V. Ignatenko
Organic Chemistry
  • 14 Downloads

Conclusions

  1. 1.

    Hydroboration of 1,1-tetra- and 1,1-pentamethyleneallene with 9-borabicylo[3.3.1]-nonane has given. 9-(3,3-tetramethyleneallyl)- and 9-(3,3-pentamethyleneallyl)-9-borabicyclo-[3.3.1]nonanes.

     
  2. 2.

    A new method has been developed for the synthesis of 1-substituted 1-vinylcycloalkanes by allylboration of carbonyl compounds and ethoxyacetylene with diorganylborylethylidenecycloalkanes.

     

Keywords

Carbonyl Nonane Carbonyl Compound Ethoxyacetylene 

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Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • Yu. N. Bubnov
    • 1
  • V. I. Zheludeva
    • 1
  • A. V. Ignatenko
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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