Conclusions
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1.
In the telomerization of acrylic monomers with mercaptans, the change from initiation by peroxides to initiation by metal complexes leads to a significant change in the nature of the distribution of the homologs in favor of the adduct.
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2.
The distribution of the telomer homologs in reactions of n-butyl mercaptan with acrylonitrile, methyl acrylate, and methyl methacrylate with initiation by carbonyls of Mn, Mo, and Cr, in contrast to peroxide initiation, is practically insensitive to a change in the ratio of the reagents.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 376–381, February, 1989.
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Churkina, T.D., Petrova, R.G., Dostovalova, V.I. et al. Reactions of acrylic monomers with mercaptans in the presence of metal carbonyls or peroxides. Russ Chem Bull 38, 325–329 (1989). https://doi.org/10.1007/BF00953622
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DOI: https://doi.org/10.1007/BF00953622