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Synthesis based on electrogenerated carbenes. 3. Electrochemical oxidation of dinitromethylides as a route to generation of dinitrocarbene

  • Orgamic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The electrochemical oxidation of S and Se dinitromethylides on a Pt anode in absolute MeCN is accompanied by the fragmentation of the molecule at the heteratom-ylide C atom bond with the proabable formation of dinitrocarbene.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. A. Petrosyan, M. E. Niyazymbetov, A. A. Fainzil'berg, S. A. Shevelev & V. V. Semenov

Authors
  1. V. A. Petrosyan
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  2. M. E. Niyazymbetov
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  3. A. A. Fainzil'berg
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  4. S. A. Shevelev
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  5. V. V. Semenov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 356–360, February, 1989.

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Petrosyan, V.A., Niyazymbetov, M.E., Fainzil'berg, A.A. et al. Synthesis based on electrogenerated carbenes. 3. Electrochemical oxidation of dinitromethylides as a route to generation of dinitrocarbene. Russ Chem Bull 38, 305–309 (1989). https://doi.org/10.1007/BF00953618

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  • DOI: https://doi.org/10.1007/BF00953618

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