Conclusions
-
1.
The influence of the components of the effect of the structural reorganization of the anionic fragments of monalkylbenzenes and nitroalkanes on the kinetics of their ionization was determined.
-
2.
A model of the mechanism of the elementary act in the ionization of monoalkylbenzenes and nitroalkanes in a polar medium, which takes into account the effects of the reorganization of the solvent, the geometric structure of the reactants, and the redistribution of the electron density in them, has been proposed.
Similar content being viewed by others
Literature cited
E. D. German and A. M. Kuznetsov, J. Chem. Soc. Faraday Trans. II,77, No. 12, 2203 (1981).
R. R. Dogonadze and A. M. Kuznetsov, Itogi Nauki Tekh., Fiz. Khim. Kinet.,2, Chap. 3–5 (1973).
N. G. Zharova, I. O. Shapiro, I. A. Misurkin, and É. D. German, Izv. Akad. Nauk SSSR, Ser. Khim., No. 2, 361 (1987).
P. G. Mezey, A. J. Kresge, and I. G. Csizmadia, Can. J. Chem.,54, No. 11, 2526 (1976).
K. S. Krasnov, N. V. Filippenko, V. A. Bobkova, et al., Molecular Constants of Inorganic Compounds [in Russian], Khimiya, Leningrad (1979), pp. 279–281.
Ya. K. Syrkin and M. E. Dyatkina, Chemical Bonding and Molecular Structure [in Russian], GosNTIKhL, Moscow-Leningrad (1946), p. 203.
W. J. Orville-Thomas (ed.), Internal Rotation of Molecules, Wiley, London-New York (1974).
É. D. German and A. N. Kuznetsov, Izv. Akad. Nauk SSSR, Ser. Khim., No. 1, 77 (1989).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 318–325, February, 1989.
Rights and permissions
About this article
Cite this article
Zharova, N.G., German, É.D., Kuznetsov, A.M. et al. Kinetics of the ionization of monoalkylbenzenes and nitroalkanes in polar solvents. 1. Model of reaction and expression for rate constant. Russ Chem Bull 38, 270–276 (1989). https://doi.org/10.1007/BF00953612
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00953612