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Structure of 1,1-di(tert-butylperoxy)cyclohexane

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

From the example of 1,1-di(tert-butylperoxy)cyclohexane it was shown that not only intramolecular steric interactions (the type of substituent at the O-O bond) but also the influence of crystal field forces have a substantial effect on the conformation of the peroxide group in the crystals of peroxyketals of cyclanes.

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Authors and Affiliations

  1. Institute of Chemical Physics, A. N. Nesmeyanov Institute of Organoelemental Compounds, Academy of Sciences of the USSR, Moscow

    A. Yu. Kosnikov, V. L. Antonovskii, S. V. Lindeman, Yu. T. Struchkov & E. V. Fedorova

Authors
  1. A. Yu. Kosnikov
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  2. V. L. Antonovskii
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  3. S. V. Lindeman
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  4. Yu. T. Struchkov
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  5. E. V. Fedorova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 294–297, February, 1989.

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Kosnikov, A.Y., Antonovskii, V.L., Lindeman, S.V. et al. Structure of 1,1-di(tert-butylperoxy)cyclohexane. Russ Chem Bull 38, 247–249 (1989). https://doi.org/10.1007/BF00953606

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  • DOI: https://doi.org/10.1007/BF00953606

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