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Negative ion mass spectrometry and stereochemistry of organic compounds. 7. Phenoxybenzyl esters of 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropane-carboxylic acid

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The stereospecific fragmentation of 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid α-cyano-3-phenoxybenzyl ester was found under conditions of resonant capture of electrons of epithermal energies with dissociation of HCN. The stereospecific collection of fragment ions allows not only the identification of one of the diastereoisomers, but also the quantitative (≥5%) determination of it in a mixture of racemates.

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Literature cited

  1. V. I. Khvostenko, V. A. Mazunov, I. I. Furlei, et al., Zh. Obshch. Khim.,44, 146 (1974).

    Google Scholar 

  2. G. A. Tolstikov, V. S. Fal'ko, L. A. Baltina, and V. I. Khvostenko, Izv. Akad. Nauk SSSR, Ser. Khim., 1051 (1977).

  3. L. A. Baltina, V. S. Fal'ko, V. I. Khvostenko, and G. A. Tolstikov, Zh. Obshch, Khim.,47, 2379 (1977).

    Google Scholar 

  4. I. I. Furlei, B. K. Mavrodiev, É. É. Shul'ts, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2477 (1985).

  5. I. I. Furlei, V. N. Odinokov, V. I. Khvostenko, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 330 (1981).

  6. V. I. Khvostenko, G. A. Tolstikov, I. I. Furlei, et al., in: Chemistry and Physical Chemistry of Monomers [in Russian], Bashkir. Fil. Akad. Nauk SSSR, Ufa (1975), p. 37.

    Google Scholar 

  7. L. A. Baltina, I. I. Furlei, P. F. Vlad, et al., Khim. Prir. Soedin., 454 (1978).

  8. M. Elliott, A. Farnham, N. Janes, et al., Nature (London),248. 710 (1974).

    Google Scholar 

  9. M. Elliott, A. Farnham, N. Janes, et al., Nature (London),246. 169 (1973).

    Google Scholar 

  10. V. I. Khvostenko, V. A. Mazunov, V. S. Fal'ko, et al., Khim. Fiz.,1, 915 (1982).

    Google Scholar 

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Authors and Affiliations

  1. Physics and Mathematics Branch, Bashkir Scientific Center, Ural' Branch, Academy of Sciences of the USSR, Ufa

    V. A. Mazunov, M. V. Muftakhov, Yu. F. Baranov, F. É. Galin & G. A. Tolstikov

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  1. V. A. Mazunov
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  2. M. V. Muftakhov
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  3. Yu. F. Baranov
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  4. F. É. Galin
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  5. G. A. Tolstikov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 291–294, February, 1989.

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Mazunov, V.A., Muftakhov, M.V., Baranov, Y.F. et al. Negative ion mass spectrometry and stereochemistry of organic compounds. 7. Phenoxybenzyl esters of 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropane-carboxylic acid. Russ Chem Bull 38, 244–246 (1989). https://doi.org/10.1007/BF00953605

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  • DOI: https://doi.org/10.1007/BF00953605

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