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Properties of lithium tetraalkylborate complexes in adsorption and desorption of oxygen

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Lithium tert-butyltrialkylborates are capable of chemisorbing oxygen. The activation energy for thermal desorption of oxygen from [t-C4H9OB(OR)3]Li·nO2 at 298–548 K increases with decreasing degree of O2 sorption and with increasing length of the alkyl substituent; for complexes with R=n-C4H9, n-C7H15, and n-C10H21, the values increase from 48.90 to 70.92 kJ/mole.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry, Siberian Branch, Academy of Sciences of the USSR, Tomsk

    Z. T. Dmitrieva, I. G. Ryzhikova & V. I. Erofeev

Authors
  1. Z. T. Dmitrieva
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  2. I. G. Ryzhikova
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  3. V. I. Erofeev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 251–253, February, 1989.

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Dmitrieva, Z.T., Ryzhikova, I.G. & Erofeev, V.I. Properties of lithium tetraalkylborate complexes in adsorption and desorption of oxygen. Russ Chem Bull 38, 209–211 (1989). https://doi.org/10.1007/BF00953597

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  • DOI: https://doi.org/10.1007/BF00953597

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