Conclusions
The heats of dissolution of hydrogen peroxide in water have been measured, and on the basis of this we have calculated the standard enthalpies of formation of KF and KF·nH2O2 (where n=1–3). We have also calculated the enthalpy of the combination of H2O2ℓ to KFcr.
Similar content being viewed by others
Literature cited
J. M. Adams and R. G. Pritchard, Acta Crystallogr.,B33, No. 12, 3650 (1977).
M. A. A. F. de C. T. Carrondo, W. P. Griffith, D. P. Jones, and A. C. Spapski, J. Chem. Soc. Dalton Trans., No. 23, 2323 (1977).
J. M. Adams and R. G. Pritchard, Acta Crystallogr.,B35, No. 8, 1759 (1979).
V. A. Sarin, V. Ya. Dudarev, T. A. Dobrynina, et al., Kristallografiya,21, No. 5, 929 (1976).
V. A. Sarin, V. Ya. Dudarev, T. A. Dobrynina, et al., Kristallografiya,22, No. 5, 982 (1977).
E. P. Kirpichev, Yu. I. Rubtsov, K. V. Timova, and V. Ya. Rosolovskii, Zh. Neorg. Khim.,28, No. 7, 1858 (1983).
N. V. Krivtsov and T. A. Dobrynina, Thesis of Speeches Presented at the All-Union Meeting on the Inorganic Chemistry of Peroxide Compounds [in Russian], Riga (1973), p. 156.
K. V. Timova, I. P. Gelyuk, and V. Ya. Rosolovskii, Zh. Neorg. Khim.,33, No. 6, 1589 (1988).
Yu. N. Matyushin, T. S. Kon'kova, A. B. Vorob'ev, et al., Inventor's Corticate No. 176,442 (USSR), Byull. Izobret., No. 13 (1980).
A. B. Vorob'ev, Yu. N. Matyushin, and B. P. Larionov, 9th All-Union Conference on Calorimetry and Chemical Thermodynamics, Tbilisi, (1982), p. 460.
V. B. Parker, Thermal Properties of Aqueous Uni-Univalent Electrolytes, Washington D. C., NSRDCNB52m (1965).
CODATA Recommended Key Values for Thermodynamics. 1977. J. Chem. Thermodyn.,10, 903 (1978).
V. P, Glushko (ed.), Thermal Constants of Substances [in Russian], Moscow, Nos. 1–10, (1965–1981).
M. E. Efimov, and V. A. Medvedev, Reviews on Thermophysical Properties of Substances [in Russian], IVTAN, Moscow, No. 3(41), (1963).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 247–250, February, 1989.
Rights and permissions
About this article
Cite this article
Timova, K.V., Kon'kova, T.S., Matyushin, Y.N. et al. Thermochemical properties of potassium fluoride peroxohydrates. Russ Chem Bull 38, 205–208 (1989). https://doi.org/10.1007/BF00953596
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00953596