Three-dimensional structure of substituted oxiranes

8. Conformation of methyl-substituted nitrooxiranes
  • B. A. Arbuzov
  • A. I. Donskova
  • S. G. Vul'fson
  • N. A. Sokolov
  • A. N. Vereshchagin
Physical Chemistry
  • 17 Downloads

Conclusions

  1. 1.

    Introduction of a geminal CH3 group does not change the conformation of nitrooxirane.

     
  2. 2.

    A cis-vicinal CH3 group causes the NO3 group to rotate 25° in the direction that wil favor reduction of steric hindrance.

     

Keywords

Steric Hindrance Oxiranes Favor Reduction 

Literature cited

  1. 1.
    A. R. Mochel, C. O. Britt, and J. E. Boggs, J. Chem. Phys.,58, 3221–3229 (1973).Google Scholar
  2. 2.
    A. N. Vereshchagin, A. I. Donskova, N. A. Sokolov, and S. G. Vul'fson, Izv. Akad. Nauk SSSR, Ser. Khim., 1761–763 (1979).Google Scholar
  3. 3.
    L. E. L. Sutton (editor), Tables of Interatomic Distances and Configurations in Molecules and Ions, Chemical Society (1958).Google Scholar
  4. 4.
    Pandy G. K. Krishnaji, Indian J. Pure Appl. Phys.,8, 261–265 (1970).Google Scholar
  5. 5.
    N. A. Sokolov, Yu. G. Chernov, and Yu. V. Glazkov, Zh. Org. Khim.,8, 2325–2327 (1972).Google Scholar

Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • B. A. Arbuzov
    • 1
  • A. I. Donskova
    • 1
  • S. G. Vul'fson
    • 1
  • N. A. Sokolov
    • 1
  • A. N. Vereshchagin
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryKazan Branch of the Academy of Sciences of the USSRUSSR

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