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Structure of some pyridyl-hydroxyazo compounds in solution

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The compounds 2-pyridylazoresorcinol, 2-(2-pyridylazo)-1-naphthol, and l-(2-pyridylazo)-2-naphthol exist in solution in organic solvents mainly as the quinonehydrazone form, while 1-(2-pyridylazo)-4-naphthol exists as the azo form.

  2. 2.

    It was postulated that the reason for stabilizing the quinonehydrazone form is the presence of a 2-pyridyl substituent and an intramolecular hydrogen bond in the studied o-hydroxyazo compounds.

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Authors and Affiliations

  1. V. I. Vernadskii Institute of Geochemistry and Analytical Chemistry, Academy of Sciences of the USSR, Moscow

    L. A. Fedorov, N. I. Grebenshchikov, T. G. Akimova & A. N. Ermakov

Authors
  1. L. A. Fedorov
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  2. N. I. Grebenshchikov
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  3. T. G. Akimova
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  4. A. N. Ermakov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 927–929, April, 1983.

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Fedorov, L.A., Grebenshchikov, N.I., Akimova, T.G. et al. Structure of some pyridyl-hydroxyazo compounds in solution. Russ Chem Bull 32, 841–843 (1983). https://doi.org/10.1007/BF00953491

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  • DOI: https://doi.org/10.1007/BF00953491

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