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Reaction of 1, 3, 2-oxazaphospholanes with acid chlorides of trivalent phosphorus

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reaction of oxazaphospholanes with acid chlorides of trivalent phosphorus takes place with the cleavage of exo- or endocyclic P-N bonds. The opening of the ring produces diphosphorylated alkanolamines, which are converted as a result of disproportionation into 1,3,2-diheterophospholanes, the latter being products of the exchange of exocyclic substituents.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    M. A. Pudovik, I. L. Ostanina & A. N. Pudovik

Authors
  1. M. A. Pudovik
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  2. I. L. Ostanina
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  3. A. N. Pudovik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 903–907, April, 1983.

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Pudovik, M.A., Ostanina, I.L. & Pudovik, A.N. Reaction of 1, 3, 2-oxazaphospholanes with acid chlorides of trivalent phosphorus. Russ Chem Bull 32, 821–824 (1983). https://doi.org/10.1007/BF00953486

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  • DOI: https://doi.org/10.1007/BF00953486

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