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Telomerization of propylene by bromoform

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The telomerization of propylene by bromoform leads to the formation of telomer homologs with the general formula CHBr2(CH2CHCH3)nBr. Telomers with n=1 and 2 were isolated. The first individual chain transfer constant (C1) in this telomerization is about 150.

  2. 2.

    In addition of bromoform to propylene proceeds largely at theα-carbon atom (>90%) and to a slight extent at theβ-carbon atom of the double bond. This leads to the formation of adducts CHBr2CH2CHBrCH3 and CHBr2CH(CH3)CH2Br.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    T. T. Vasil'eva, L. F. Germanova, V. I. Dostovalova, B. V. Nelyubin & R. Kh. Freidlina

Authors
  1. T. T. Vasil'eva
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  2. L. F. Germanova
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  3. V. I. Dostovalova
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  4. B. V. Nelyubin
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  5. R. Kh. Freidlina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 872–877, April, 1983.

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Vasil'eva, T.T., Germanova, L.F., Dostovalova, V.I. et al. Telomerization of propylene by bromoform. Russ Chem Bull 32, 794–797 (1983). https://doi.org/10.1007/BF00953479

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  • DOI: https://doi.org/10.1007/BF00953479

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