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Telomerization of 1-pentene by chloroform and the chemical transformation of the resultant telomers

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of 1-pentene with CHCl3 induced by peroxides yields CCl3(CH2CHC3H7)nH (n=1, 2) telomers in a 10∶1 ratio: 1,1,1-trichlorohexane and 1,1,1-trichloro-3-propyloctane.

  2. 2.

    1,1,1-Trichlorohexane is reduced in good yield to 1,1-dichlorohexane by isopropyl alcohol in the presence of Fe(CO)5. This reduction is accompanied by the rearrangement of CCl2(CH2)3CH2CH3 with 1, 5-hydrogen migration. Under the conditions selected, there is virtually no 1,6 -hydrogen migration from the CH3 group.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. V. Kruglova & T. N. Skokova

Authors
  1. N. V. Kruglova
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  2. T. N. Skokova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 867–872, April, 1983.

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Kruglova, N.V., Skokova, T.N. Telomerization of 1-pentene by chloroform and the chemical transformation of the resultant telomers. Russ Chem Bull 32, 790–794 (1983). https://doi.org/10.1007/BF00953478

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  • DOI: https://doi.org/10.1007/BF00953478

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