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Catalytic properties of group VIII metal compounds supported on a polymeric carrier

3. Nickel and cobalt complexes supported on carriers containing coordination groups based on phosphorus in the hydrogenation and isomerization reactions of allylbenzene

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Nickel and cobalt complexes supported on a polymeric carrier containing phosphinate or phosphonate groups catalyze the hydrogenation and isomerization of allylbenzene. Nickel complexes were more active than cobalt complexes.

  2. 2.

    A reduction in the electron-accepting properties of the substituent on the phosphorus atom promoted an increase in the catalytic activity of the synthesized systems. Complexes containing a cyclohexyloxy substituent on the phosphorus atom displayed the greatest activity.

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Literature cited

  1. L. N. Sukhobok, G. P. Potapov, V. G. Luksha, V. N. Krutii, and B. D. Polkovnikov, Izv. Akad. Nauk SSSR, Ser. Khim., 2307 (1982).

  2. L. N. Sukhobok, G. P. Potapov, V. G. Luksha, V. N. Krutii, and B. D. Polkovnikov, Izv. Akad. Nauk SSSR, Ser. Khim., 2310 (1982).

  3. Yu. V. Karyakin and I. I. Angelov, Pure Chemical Substances [in Russian], Khimiya, Moscow (1974), pp. 208, 292.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    L. N. Sukhobok, G. P. Potapov, B. D. Polkovnikov, V. G. Luksha & V. N. Krutii

Authors
  1. L. N. Sukhobok
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  2. G. P. Potapov
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  3. B. D. Polkovnikov
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  4. V. G. Luksha
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  5. V. N. Krutii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 836–838, April, 1983.

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Sukhobok, L.N., Potapov, G.P., Polkovnikov, B.D. et al. Catalytic properties of group VIII metal compounds supported on a polymeric carrier. Russ Chem Bull 32, 763–764 (1983). https://doi.org/10.1007/BF00953471

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  • DOI: https://doi.org/10.1007/BF00953471

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