Skip to main content
SpringerLink
Log in

19F NMR study of transmission capability of Hg-S and Sn-S binuclear bridge groupings

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

19F-{1H} NMR has been used to investigate the comparative efficiency of transfer of electronic effects of substituants (EES) through metal-sulfur binuclear bridge groupings, in model systems ArnMSC6H4F−4 (M=Hg, Sn, CH2; n=1, 3). In transmission capability, Hg-S and Sn-S are very little different from the mononuclear analogs Hg and Sn. The order of arrangement of the units in the Hg-S bridge has no effect on the transmission capability. The CH2-S bridge has a greater transmission capability than Hg-S. The EES transfer efficiency through the metal-sulfur bridge is much lower in coordinating polar solvents. An estimate has been made of the relative contributions of dipole-dipole and coordination interactions with the solvent to the overall effect in lowering the transmission capability.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. N. Nesmeyanov, S. I. Pombrik, E. V. Polunkin, L. S. Golovchenko, A. S. Peregudov, D. N. Kravtsov, and É. I. Fedin, Izv. Akad. Nauk SSSR, Ser. Khim., 763 (1981).

  2. S. I. Pombrik, E. V. Polunkin, A. S. Peregudov, É. M. Fedin, and D. N. Kravtsov, Izv. Akad. Nauk SSSR, Ser. Khim., 1289 (1982).

  3. S. I. Pombrik, A. S. Peregudov, É. I. Fedin, and D. N. Kravtsov, Izv. Akad. Nauk SSSR, Ser. Khim., 2375 (1982).

  4. P. W. Wells, E. Ehrenson, and R. W. Taft, Progr. Phys. Org. Chem.,6, 204 (1968).

    Google Scholar 

  5. A. N. Nesmeyanov, D. N. Kravtsov, L. S. Golovchenko, A. S. Peregudov, P. O. Okulevich, and É. I. Fedin, Izv. Akad. Nauk SSSR, Ser. Khim., 1664 (1979).

  6. A. N. Nesmeyanov, D. N. Kravtsov, B. A. Kvasov, E. M. Roklina, V. M. Pachevskaya, L. S. Golovchenko, and É. I. Fedin, J. Organomet. Chem.,38, 307 (1972).

    Google Scholar 

  7. W. F. Reynolds and G. K. Hamer, J. Am. Chem. Soc.,98, 7296 (1976).

    Google Scholar 

  8. W. Adcock and M. I. Dewar, J. Am. Chem. Soc.,89, 379 (1967).

    Google Scholar 

  9. D. N. Kravtsov, L. S. Golovchenko, A. S. Peregudov, P. O. Okulevich, and É. I. Fedin, Izv. Akad. Nauk SSSR, Ser. Khim., 1664 (1979).

  10. S. K. Dayal and R. W. Taft, J. Am. Chem. Soc.,95, 5595 (1973).

    Google Scholar 

  11. T. R. Griffiths and D. C. Pugh, Coord. Chem. Rev.,29, 129 (1979).

    Google Scholar 

  12. R. Okawara and M. Wada, Adv. Organomet. Chem.,5, 137 (1967).

    Google Scholar 

  13. A. N. Nesmeyanov, D. N. Kravtsov, and S. I. Pombrik, Izv. Akad. Nauk SSSR, Ser. Khim., 474 (1981).

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    S. I. Pombrik, L. S. Golovchenko, A. S. Peregudov, É. I. Fedin & D. N. Kravtsov

Authors
  1. S. I. Pombrik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. S. Golovchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. S. Peregudov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. É. I. Fedin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. D. N. Kravtsov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 803–809, April, 1983.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pombrik, S.I., Golovchenko, L.S., Peregudov, A.S. et al. 19F NMR study of transmission capability of Hg-S and Sn-S binuclear bridge groupings. Russ Chem Bull 32, 732–737 (1983). https://doi.org/10.1007/BF00953465

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00953465

Keywords

Search

Navigation