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Inhibition of enantioselective hydrogenation of ethyl acetoacetate

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

In enantioselective hydrogenation of ethyl acetoacetate on a Raney nickel catalyst modified with (+)-tartaric acid, we found an inhibiting effect of the reaction products, namely, racemic ethylβ-hydroxybutyrate and (-)-ethylβ-hydroxybutyrate, and also of acetic acid, pyridine, and thiophene, and we determined their relative adsorption coefficients.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. V. Chernysheva, I. P. Murina & E. I. Klabunovskii

Authors
  1. V. V. Chernysheva
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  2. I. P. Murina
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  3. E. I. Klabunovskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 757–760, April, 1983.

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Chernysheva, V.V., Murina, I.P. & Klabunovskii, E.I. Inhibition of enantioselective hydrogenation of ethyl acetoacetate. Russ Chem Bull 32, 689–692 (1983). https://doi.org/10.1007/BF00953457

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  • DOI: https://doi.org/10.1007/BF00953457

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