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Mechanism of oxidation of slightly reduced 12-molybdovanadophosphate blues with oxygen in solution

  • Inorganic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Data on the thermodynamics of the oxidation of 12-molybdovanadophosphate blues by oxygen indicate a low probability for one-electron transfer in the reaction of the blue with oxygen and are consistent with the transfer of two, three, or four electrons.

  2. 2.

    Data on the kinetics of the oxidation of the blues by hydrogen peroxide and oxygen confirm the previously proposed mechanism for the oxidation of weakly reduced blues by oxygen, including the transfer of three electrons in the complex of 02 with the blue.

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Literature cited

  1. I. V. Kozhevnikov and K. I. Matveev, Usp. Khim.,51, 1875 (1982).

    Google Scholar 

  2. I. V. Kozhevnikov, S. M. Kulikov, V. E. Taraban'ko, and K. I. Matveev, Dokl. Akad. Nauk SSSR,240, 892 (1978).

    Google Scholar 

  3. I. V. Kozhevnikov, Yu. V. Burov, and K. I. Matveev, Izv. Akad. Nauk SSSR, Ser. Khim., 2428 (1981).

  4. V. M. Berdnikova, L. I. Kuznetsova, K. I. Matveev, N. P. Kirik, and É. N. Yurchenko, Koordinats. Khim.,5, 78 (1979).

    Google Scholar 

  5. L. I. Kuznetsova, L. G. Detusheva, É. N. Yurchenko, and K. I. Matveev, in: Investigation of the Characteristics and Application of Heteropoly Acids in Catalysis [in Russian], Nauka, Novosibirsk (1978), p. 100.

    Google Scholar 

  6. V. F. Odyakov, L. I. Kuznetsova, and K. I. Matveev, Zh. Neorg. Khim.,23, 457 (1978).

    Google Scholar 

  7. D. P. Smith and M. T. Pope, Inorg. Chem.,12, 331 (1973).

    Google Scholar 

  8. I. P. Alimarin, E. N. Dorokhova, L. P. Kazanskii, and G. V. Prokhorova, Zh. Anal. Khim.,35, 2000 (1980).

    Google Scholar 

  9. A. M. Sukhotin (editor), Textbook of Electrochemistry [in Russian], Khimiya, Leningrad (1981).

    Google Scholar 

  10. Chemist's Handbook [in Russian], Vol. 3, Khimiya, Moscow-Leningrad (1964), p. 319.

  11. P. Souchay, F. Chauveau, and P. Courtin, Bull. Soc. Chim. France, 2384 (1968).

  12. A. Samuni, D. Meisel, and G. Czapski, J. Chem. Soc. Dalton Trans., 1273 (1972).

  13. L. I. Kuznetsova, É. N. Yurchenko, R. I. Maksiniovskaya, N. P. Kirik, and K. I. Matveev, Koord. Khim.,3, 52 (1977).

    Google Scholar 

  14. L. I. Kuznetsova, V. M. Berdnikov, É. N. Yurchenko, K. I. Matveev, and N. P. Kirik, in: Investigation of Characteristics and Application of Heteropoly Acids in Catalysis [in Russian], Nauka, Novosibirsk (1978), p. 197.

    Google Scholar 

  15. I. V. Kozhevnikov, O. A. Kholdeeva, M. A. Fedotov, and K. I. Matveev, Izv. Akad. Nauk SSSR, Ser. Khim., 717 (1983).

  16. V. M. Berdnikov, L. L. Makarshin, and L. S. Ryvkina, React. Kinet. Catal. Lett.,9, 205 (1978).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    I. V. Kozhevnikov

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  1. I. V. Kozhevnikov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 721–726, April, 1983.

The author thanks S. M. Kulikov for assistance in the experiments.

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Kozhevnikov, I.V. Mechanism of oxidation of slightly reduced 12-molybdovanadophosphate blues with oxygen in solution. Russ Chem Bull 32, 655–659 (1983). https://doi.org/10.1007/BF00953451

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  • DOI: https://doi.org/10.1007/BF00953451

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