Conclusions
The kinetics of the reactions of VO2+ with 12-tungstovanadophosphates (HPA) in aqueous solution are fully analogous with the kinetics of the reactions of VO2+ with 12-molybdovanadophosphates. The obtained data support the electron transfer mechanism for the reactions of the HPAs with VO2+.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 717–721, April, 1983.
The authors express their gratitude to Yu. V. Burov and V. E. Taraban'ko for assistance in the chemical investigations and also to R. I. Maksimovskaya for the ESR measurements.
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Kozhevnikov, I.V., Kholdeeva, O.A., Fedotov, M.A. et al. Kinetics and mechanism of reaction of V02+ with 12-tungstovanadophosphates in aqueous solution. Russ Chem Bull 32, 651–654 (1983). https://doi.org/10.1007/BF00953450
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DOI: https://doi.org/10.1007/BF00953450