Conclusions
-
1.
The rate constant for the reaction of N(4S) atoms with methane at room temperature is less than 10−17 cm3/sec.
-
2.
The rate constant for the reaction of N(4S) atoms with methyl iodide at room temperature is (3.4±1.8)·10−16 cm3/sec.
This is a preview of subscription content, log in via an institution to check access.
Literature cited
V. Ya. Basevich, Khim. Fiz.,5, 925 (1986).
S. Miyazaki and S. Takahashi, Mem. Defense Acad. Math. Phys. Chem. Eng.,6, 411 (1966).
S. Miyazaki and S. Takahashi, Bull. Chem. Soc. Jpn.,41, 1456 (1968).
S. Takahashi, Mem. Defense Acad. Jpn.,12, 149 (1972).
E. N. Aleksandrov, Chemical Sciences Doctoral Dissertation, Moscow (1986).
E. N. Aleksandrov, V. S. Arutyunov, I. V. Dubrovina, and S. N. Kozlov, Izv. Akad. Nauk SSSR, Ser. Khim., 764 (1983).
S. N. Kozlov, E. N. Aleksandrov, B. E. Zhestkov, and M. U. Kislyuk, Izv. Akad. Nauk SSSR, Ser. Khim., 2449 (1987).
V. N. Kondrat'ev, Handbook on Rate Constants for Gas-Phase Reactions [in Russian], Izd. Nauka, Moscow (1970).
I. M. Campbell and S. B. Neal, Faraday Disc. Chem. Soc., No. 53, 72 (1972).
S. Miyazaki and S. Takahashi, Mem. Defense Acad. Jpn.,14, 63 (1974).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2407–2409, October, 1988.
The authors thank B. Ya. Basevich for a discussion of these results.
Rights and permissions
About this article
Cite this article
Aleksandrov, E.P., Vedeneev, V.I., Kozlov, S.N. et al. Rate constants of the reactions of N(4S) with CH4 and CH3I. Russ Chem Bull 37, 2170–2171 (1988). https://doi.org/10.1007/BF00953431
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00953431