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Efficient method for the preparation of substituted benzaldehydes by the oxidation of cyclooctatetraene, cycloheptatriene and their derivatives by molecular oxygen in the presence of palladium complexes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    An efficient preparative method has been developed for the synthesis of benzaldehydes by the oxidation of cyclooctatetraenes and cycloheptatrienes by molecular oxygen in the presence of the PdCl2-CuCl system.

  2. 2.

    Monosubstituted cyclooctatetraenes are converted predominantly to meta-substituted benzaldehydes. A mechanism was proposed for this reaction.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Science Center, Urals Branch, Academy of Sciences of the USSR, Ufa

    G. A. Dzhemileva, V. N. Odinokov & U. M. Dzhemilev

Authors
  1. G. A. Dzhemileva
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  2. V. N. Odinokov
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  3. U. M. Dzhemilev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2403–2405, October, 1988.

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Dzhemileva, G.A., Odinokov, V.N. & Dzhemilev, U.M. Efficient method for the preparation of substituted benzaldehydes by the oxidation of cyclooctatetraene, cycloheptatriene and their derivatives by molecular oxygen in the presence of palladium complexes. Russ Chem Bull 37, 2165–2167 (1988). https://doi.org/10.1007/BF00953429

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  • DOI: https://doi.org/10.1007/BF00953429

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