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Transformed steroids. 171. Heterocyclization in the 16α,17α-epiminopregn-5-ene-3β,21-diol-20-one series

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The transformation of 21-0,N-isopropylidene derivatives of 16α,17α-epiminopregn-5-ene-2β,21-diol-20-one into 20-0,N-isopropylidene derivatives of 16α,17α-epiminopregn-5-ene-3β,20-diol-20-one was discovered, and, based on this, a new variant of the synthesis of 16α,17α-epiminopregn-5-ene-3β,21-diol-20-one-3′,21-diacetate was proposed.

  2. 2.

    A new class of steroids with additional tetrahydrofuran and 1′,3 -imidazolidine-2′thione rings E and F, respectively, was synthesized.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. M. Turuta, A. V. Kamernitskii, T. M. Fadeeva, A. Pabinger, V. S. Bogdanov, S. V. Lindeman & Yu. T. Struchkov

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  1. A. M. Turuta
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  2. A. V. Kamernitskii
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  3. T. M. Fadeeva
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  4. A. Pabinger
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  5. V. S. Bogdanov
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  6. S. V. Lindeman
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  7. Yu. T. Struchkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2392–2398, October, 1988.

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Turuta, A.M., Kamernitskii, A.V., Fadeeva, T.M. et al. Transformed steroids. 171. Heterocyclization in the 16α,17α-epiminopregn-5-ene-3β,21-diol-20-one series. Russ Chem Bull 37, 2156–2161 (1988). https://doi.org/10.1007/BF00953426

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  • DOI: https://doi.org/10.1007/BF00953426

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