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Determining role of nonbonding intermolecular Br...Br interactions in the crystal structure of p-bromo-[N′-(5-nitrofurfurylidene)benzhydrazide

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

An x-ray diffraction structural investigation of the non-light-sensitive crystals of p-bromo-[N′-(5-nitrofurfurylidene)]benzhydrazide showed anomalously short intermolecular Br...Br contacts, indicating a specific interaction between these atoms, which hinders packing of the ketohydrazone molecules in stacks in a head-to-tail pattern as found in previously studied light-sensitive crystals of compounds in this class.

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Literature cited

  1. S. M. Aldoshin, A. N. Chekhlov, E. G. Atovmyan, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1312 (1988).

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  4. S. M. Aldoshin, L. O. Atovmyan, O. A. Kozina, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1567 (1988).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2308–2313, October, 1988.

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Aldoshin, S.M., Kozina, O.A., Atovmyan, E.G. et al. Determining role of nonbonding intermolecular Br...Br interactions in the crystal structure of p-bromo-[N′-(5-nitrofurfurylidene)benzhydrazide. Russ Chem Bull 37, 2077–2080 (1988). https://doi.org/10.1007/BF00953408

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  • DOI: https://doi.org/10.1007/BF00953408

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