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Thermal analysis and mass spectra of sulfur-containing iron carbonyl complexes

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The activation energy for the thermal decomposition of complexes with Fe2(CO)6S2 frameworks amounts to 103–144 kJ/mole.

  2. 2.

    Decarbonylation and splitting off of the hydrocarbon part of the molecule is the general pattern of behavior of iron carbonyl compounds with sulfur ligands on heating and under electron bombardment.

  3. 3.

    In complexes containing a norbornadiene fragment, a reverse Diels-Alder reaction takes place under electron bombardment, in addition to splitting off of norbornadiene.

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Literature cited

  1. N. A. Nechitailo, M. A. Dzyubina, V. D. Tyurin, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 655 (1987).

  2. E. A. Chernyshev, O. V. Kuz'min, A. V. Lebedev, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2390 (1984).

  3. R. B. King, J. Am. Chem. Soc.,90, 1429 (1968).

    Google Scholar 

  4. N. S. Nametkin, B. I. Kolobkov, V. D. Tyurin, et al., J. Organomet. Chem.,276, 393 (1984).

    Google Scholar 

  5. B. I. Kolobkov, N. S. Nametkin, V. D. Tyurin, et al., J. Organomet. Chem.,301, 349 (1986).

    Google Scholar 

  6. A. I. Nekhaev, S. D. Alekseeva, N. S. Nametkin, et al., Neftekhimiya,26, 239 (1986).

    Google Scholar 

  7. N. S. Nametkin, V. D. Tyurin, G. G. Aleksandrov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2572 (1981).

  8. R. A. Jackson, R. Kanluen, and A. Poë, Inorg. Chem.,23, 523 (1984).

    Google Scholar 

  9. D. R. Bidinosti and N. S. McIntyre, Can. J. Chem.,45, 641 (1967).

    Google Scholar 

  10. F. A. Cotton, A. K. Fischer, and G. Wilkinson, J. Am. Chem. Soc.,81, 800 (1959).

    Google Scholar 

  11. G. A. Junk and N. J. Svec, Z. Naturforsch.,B23, No. 1, 1–9 (1968).

    Google Scholar 

  12. G. O. Piloyan, Introduction to the Theory of Thermal Analysis [in Russian], Nauka, Moscow (1965).

    Google Scholar 

  13. L. Reich, Macromol. Chem.,105, 223 (1967).

    Google Scholar 

  14. V. G. Syrkin, Chemistry and Technology of Carbonyl Materials [in Russian], Khimiya, Moscow (1972), p. 102.

    Google Scholar 

  15. M. K. Chaudhuri, A. Haas, M. Rosenburg, et al., J. Organomet. Chem.,124, 37 (1977).

    Google Scholar 

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    M. A. Dzyubina, G. N. Kuz'mina, B. I. Kolobkov & A. I. Nekhaev

Authors
  1. M. A. Dzyubina
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  2. G. N. Kuz'mina
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  3. B. I. Kolobkov
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  4. A. I. Nekhaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2286–2292, October, 1988.

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Dzyubina, M.A., Kuz'mina, G.N., Kolobkov, B.I. et al. Thermal analysis and mass spectra of sulfur-containing iron carbonyl complexes. Russ Chem Bull 37, 2057–2062 (1988). https://doi.org/10.1007/BF00953404

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  • DOI: https://doi.org/10.1007/BF00953404

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