Behavior of 1-boraadamantane complexes during chemical ionization

  • V. I. Kadentsev
  • N. G. Kolotyrkina
  • O. S. Chizhov
  • M. E. Gurskii
  • A. I. Grandberg
  • T. V. Potapova
  • Yu. N. Bubnov
Physical Chemistry
  • 18 Downloads

Conclusions

Intra- and intermolecular complexes of 1-boraadamantane during mild protolysis eliminate a hydride ion to form [M - H]+ ions. During severe protolysis (methane reactant gas) protonation of the 1-boraadamantane structure occurs with cleavage of a B-C bond.

Keywords

Methane Hydride Chemical Ionization Methane Reactant Intermolecular Complex 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    Yu. N. Bubnov, M. E. Gurskii, A. I. Grandberg, and D. G. Pershin, Tetrahedron,42, 1079 (1986).Google Scholar
  2. 2.
    B. M. Mikhailov, M. E. Gurskii, T. V. Potapova, and A. S. Shashkov, J. Organomet. Chem.,201, 81 (1980).Google Scholar
  3. 3.
    V. I. Kadentsev, O. S. Chizhov, N. G. Kolotyrkina, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2021 (1987).Google Scholar
  4. 4.
    A. A. Solov'ev, V. I. Kadentsev, and O. S. Chizhov, Usp. Khim.,48, 1193 (1979).Google Scholar
  5. 5.
    D. J. Liberato, C. C. Fenselan, and M. L. Vestal, Anal. Chem.,56, 1741 (1983).Google Scholar
  6. 6.
    R. Walder and J. L. Franklin, Int. J. Mass Spectrom. Ion Phys.,36, 85 (1980).Google Scholar
  7. 7.
    L. Dolejek, S. Hala, V. Hanus, and S. Landa, Coll. Czech. Chem. Comm.,31, 435 (1966).Google Scholar
  8. 8.
    Yu. N. Bubnov, M. E. Gurskii, and T. V. Potapova, Izv. Akad. Nauk SSSR, Ser. Khim., 1195 (1987).Google Scholar
  9. 9.
    B. M. Mikhailov, V. N. Smirnov, and V. A. Kasparov, Izv. Akad. Nauk SSSR, Ser. Khim., 2302 (1976).Google Scholar
  10. 10.
    L. G. Vorontsova, O. S. Chizhov, V. N. Smirnov, and B. M. Mikhailov, Izv. Akad. Nauk SSSR, Ser. Khim., 595 (1981).Google Scholar

Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • V. I. Kadentsev
    • 1
  • N. G. Kolotyrkina
    • 1
  • O. S. Chizhov
    • 1
  • M. E. Gurskii
    • 1
  • A. I. Grandberg
    • 1
  • T. V. Potapova
    • 1
  • Yu. N. Bubnov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

Personalised recommendations