Synthesis and steric structure of 2,2-disubstituted 5-phenyl-1,3,5-dioxaphosphorinanes

  • B. A. Arbuzov
  • O. A. Erastov
  • A. S. Ionkin
Organic Chemistry
  • 27 Downloads

Conclusions

Phenylbis(l-ethoxyalkyl)phosphines and 2,2-disubstituted 5-phenyl-l,3,5-dioxaphosphorinanes, with their conformational equilibrium shifted in the direction of the form with an axial orientation of phenyl at the phosphorus atom, were obtained by the reaction of phenylbis(hydroxymethyl)phosphine with aldehyde and ketone acetals, respectively.

Keywords

Acetal Phosphorus Aldehyde Phenyl Ketone 

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Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • B. A. Arbuzov
    • 1
  • O. A. Erastov
    • 1
  • A. S. Ionkin
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' BranchAcademy of Sciences of the USSRUSSR

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