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Electrochemical system with a soluble anode for the reductive dechlorination of 7,7-dichloronorcarane

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    An electrochemical system was proposed with a soluble metal anode for the exhaustive reduction dehalogenation of 7,7-dichloronorcarane, which permits an enhanced yield of norcarane both relative to current and substrate.

  2. 2.

    The efficiency of the metal anodes used falls in the series Al>Sn>Fe.

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Literature cited

  1. V. A. Afanas'ev, G. N. Nesterenko, B. G. Rogachev, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 11, 2637 (1982).

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  2. V. A. Afanas'ev, G. N. Nesterenko, B. G. Rogachev, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 4, 806 (1988).

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  3. M. L. Khidekel', B. G. Rogachev, V. A. Afanas'ev, and O. N. Efimov, Abstracts of the Tenth All-Union Conference on the Electrochemistry of Organic Compounds [in Russian], Novocherkassk (1980), p. 26.

  4. M. L. Khidekel', V. A. Afanas'ev, B. G. Rogachev, et al., USSR Inventor's Certificate No. 857,098; Byull. Izobret., No. 31 (1981).

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    V. A. Afanas'ev, T. G. Vaistub, L. S. Medoks, G. N. Nesterenko, T. G. Panina & B. G. Rogachev

  2. Chemistry Research Institute, N. G. Chernyshevskii Saratov State University, USSR

    V. A. Afanas'ev, T. G. Vaistub, L. S. Medoks, G. N. Nesterenko, T. G. Panina & B. G. Rogachev

Authors
  1. V. A. Afanas'ev
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  2. T. G. Vaistub
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  3. L. S. Medoks
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  4. G. N. Nesterenko
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  5. T. G. Panina
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  6. B. G. Rogachev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 955–957, April, 1989.

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Afanas'ev, V.A., Vaistub, T.G., Medoks, L.S. et al. Electrochemical system with a soluble anode for the reductive dechlorination of 7,7-dichloronorcarane. Russ Chem Bull 38, 861–862 (1989). https://doi.org/10.1007/BF00953308

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  • DOI: https://doi.org/10.1007/BF00953308

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