Conclusions
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1.
A thermal adsorption equation was proposed, which permits the calculation of adsorptional equilibria on microporous carbon adsorbents in the pre- and supercritical regions as well as in the region of the liquid state of the adsorbate using two adsorption isotherms, calculated on the basis of the VMOT, and the property of linearity of the adsorption isosteres.
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2.
The adsorption of methane on the completely microporous carbon adsorbent PAU-10 at 120–600 K and 0.1 Pa-20 MPa is described satisfactorily by the adsorption equation obtained if n is a function of temperature.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 952–955, April, 1989.
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Fomkin, A.A., Chkhaidze, é.V., Serpinskii, V.V. et al. Application of the modified volumetric micropore occupancy theory equation for the description of methane adsorption on a microporous carbon adsorbent. Russ Chem Bull 38, 858–860 (1989). https://doi.org/10.1007/BF00953307
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DOI: https://doi.org/10.1007/BF00953307