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Synthesis and structure of the dimethylamide of chlorothioformic acid and its reaction with potassium thiocyanate

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Methods for the preparation of dimethyl- and diethylamides of chlorothioformic acid of greater purity based on the reaction of tetraalkylthiuram disulfides with sulfuryl chloride are presented.

  2. 2.

    Reaction of the dimethylamide of chlorothioformic acid with potassium thiocyanate proceeds through a fast dimerization of the initially produced dimethylaminothiocarbonylisothiocyanate, followed by 1,3 (N→S) migration of the dimethylaminothiocarbonyl group to give 2-dimethylamino-4-dimethylaminothiocarbonylthio-1,3,5-thiadiazine-6-thione.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, USSR

    A. N. Pudovik, V. K. Khairullin, M. A. Vasyanina, R. M. Kamalov, O. N. Kataeva, I. A. Litvinov & V. A. Naumov

  2. Kazan Branch of the Academy of Sciences of the USSR, USSR

    A. N. Pudovik, V. K. Khairullin, M. A. Vasyanina, R. M. Kamalov, O. N. Kataeva, I. A. Litvinov & V. A. Naumov

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  1. A. N. Pudovik
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  2. V. K. Khairullin
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  3. M. A. Vasyanina
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  4. R. M. Kamalov
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  5. O. N. Kataeva
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  6. I. A. Litvinov
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  7. V. A. Naumov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 909–913, April, 1989.

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Pudovik, A.N., Khairullin, V.K., Vasyanina, M.A. et al. Synthesis and structure of the dimethylamide of chlorothioformic acid and its reaction with potassium thiocyanate. Russ Chem Bull 38, 819–822 (1989). https://doi.org/10.1007/BF00953298

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  • DOI: https://doi.org/10.1007/BF00953298

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