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Radical arylation of substituted 3-amino-1-indenthiones — Cyclic vinylogs of thioamides

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Radical arylation of 3-arylamino-2-phenyl-1-indenthiones with aryldiazonium fluoroborates or N-nitrosoacetanilide leads to the corresponding 1-arylamino-2-phenyl-3-arylthioindenes with high yield. Partial hydrolysis of the latter under the reaction conditions form 1-oxo-2-phenyl-3-arylthioindenes as by-products.

  2. 2.

    The similarity of thioamides and their vinylogs (the aminoindenthiones) in radical arylation reactions was established.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    I. I. Kandror, V. A. Usov, I. O. Bragina, T. L. Usova, V. K. Bel'skii & M. G. Voronkov

  2. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    I. I. Kandror, V. A. Usov, I. O. Bragina, T. L. Usova, V. K. Bel'skii & M. G. Voronkov

Authors
  1. I. I. Kandror
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  2. V. A. Usov
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  3. I. O. Bragina
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  4. T. L. Usova
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  5. V. K. Bel'skii
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  6. M. G. Voronkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 901–905, April, 1989.

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Kandror, I.I., Usov, V.A., Bragina, I.O. et al. Radical arylation of substituted 3-amino-1-indenthiones — Cyclic vinylogs of thioamides. Russ Chem Bull 38, 811–815 (1989). https://doi.org/10.1007/BF00953296

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  • DOI: https://doi.org/10.1007/BF00953296

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