Skip to main content
SpringerLink
Log in

Acidoligand substitution in large palladium clusters

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In an aqueous solution of potassium hexafluorophosphate, the outer-sphere acetate anions in the large cluster with the idealized formula Pd561 Phen60(OAc)180 (Phen=1,10-phenanthroline) are completely replaced by outer-sphere hexafluorophosphate anions and coordinated oxide anions.

  2. 2.

    Upon substitution of the acetate ligands, the icosahedral packing of the palladium atoms in the metal framework of the large cluster is preserved, but the distance between atoms in the outer layer increases substantially.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. V. P. Zagorodnikov, M. N. Vargaftik, D. I. Kochubei, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 253 (1986).

  2. V. P. Zagorodnikov, M. N. Vargaftik, and I. I. Moiseev, Kinet. Katal.,27, 851 (1986).

    Google Scholar 

  3. I. P. Stolyarov, M. N. Vargaftik, and I. I. Moiseev, Kinet. Katal.,28, No. 6, 1359 (1987).

    Google Scholar 

  4. M. N. Vargaftik, V. P. Zagorodnikov, I. P. Stolyarov, et al., Dokl. Akad. Nauk SSSR,284, 896 (1985).

    Google Scholar 

  5. M. N. Vargaftik, V. P. Zagorodnikov, I. P. Stolyarov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 10, 2381 (1985).

    Google Scholar 

  6. M. N. Vargaftik, T. A. Stromnova, T. S. Khodashova, et al., Koord. Khim.,7, 132 (1981).

    Google Scholar 

  7. E. G. Mednikov, N. K. Eremenko, Yu. L. Slovokhotov, and Yu. T. Struchkov, J. Organomet. Chem.,301, C35 (1986).

    Google Scholar 

  8. S. Ladas, R. A. Dulla Betta, and M. Boudart, J. Catal.,68, 246 (1978).

    Google Scholar 

  9. C. Vonsovskii, Magnetism [in Russian], Nauka, Moscow (1971).

    Google Scholar 

  10. B. K. Teo and P. A. Lee, J. Am. Chem. Soc.,101, 2815 (1979).

    Google Scholar 

  11. A. N. Naumochkin and D. I. Kochubey, Nucl. Instrum. Methods Phys. Res., 3 (1987).

  12. P. M. Maitlis, The Organic Chemistry of Palladium, Vol. 1, Academic Press, New York (1971).

    Google Scholar 

  13. M. N. Vargaftik, V. P. Zagorodnikov, I. P. Stolarov, et al., J. Chem. Soc., Chem. Commun., 937 (1985).

  14. A. M. Vlasov, K. I. Zamaraev, M. A. Kozlov, et al., Khim. Fiz.,1, 663 (1983).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    V. P. Zagorodnikov, M. N. Vargaftik, D. I. Kochubei, V. A. Likholobov, V. N. Kolomiichuk, A. N. Naumochkin, A. L. Chuvilin, V. M. Novotortsev, O. G. éllert & I. I. Moiseev

  2. Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    V. P. Zagorodnikov, M. N. Vargaftik, D. I. Kochubei, V. A. Likholobov, V. N. Kolomiichuk, A. N. Naumochkin, A. L. Chuvilin, V. M. Novotortsev, O. G. éllert & I. I. Moiseev

Authors
  1. V. P. Zagorodnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. N. Vargaftik
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. I. Kochubei
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. A. Likholobov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. N. Kolomiichuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. N. Naumochkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. L. Chuvilin
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. V. M. Novotortsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. O. G. éllert
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. I. I. Moiseev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 849–854, April, 1989.

The authors thank S. G. Sakharov for recording the NMR spectra.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zagorodnikov, V.P., Vargaftik, M.N., Kochubei, D.I. et al. Acidoligand substitution in large palladium clusters. Russ Chem Bull 38, 762–766 (1989). https://doi.org/10.1007/BF00953288

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00953288

Keywords

Search

Navigation