Skip to main content
SpringerLink
Log in

EPR study of photoreduction of adducts of 3,6-di-tert-butyl-o-benzoquinone with dichlorocarbene

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The formation of neutral and anion-radical particles was shown during the photoreduction of adducts of dichlorocarbene with 3,6-di-tert-butyl-o-benzoquinone in inert media and in the presence of amines, respectively.

  2. 2.

    The presence of thermo- and photoisomerization was shown for two forms of a neutral radical formed during the photoreduction of an adduct of 3,6-di-tert-butyl-o-benzoquinone with two dichlorocarbene fragments, consisting in opening of a three-membered ring with the formation of α,α′-dichloroalkyl radicals.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. J. K. S. Wan, Adv. Photochem.,12, No. 4, 322 (1980).

    Google Scholar 

  2. N. N. Bubnov, A. I. Prokof'ev, A. A. Volod'kin, et al., Dokl. Akad. Nauk SSSR,210, 100 (1973).

    Google Scholar 

  3. I. V. Khudyakov and V. A. Kuz'min, Usp. Khim.,14, 1748 (1975).

    Google Scholar 

  4. J. R. Koshi, K. S. Chen, and J. K. S. Wan, Chem. Phys. Lett.,73, 557 (1980).

    Google Scholar 

  5. M. I. Kabachnik, N. N. Bubnov, S. P. Solodovnikov, and A. I. Prokof'ev, Usp. Khim.,53, 487 (1984).

    Google Scholar 

  6. G. G. Lazarev, Ya. S. Lebedev, A. I. Prokof'ev, and R. R. Rakhimov, Khim. Fiz.,3, No. 6, 867 (1984).

    Google Scholar 

  7. G. G. Lazarev, Ya. S. Lebedev, A. I. Prokof'ev, and R. R. Rakhimov, Khim. Fiz.,2, No. 4, 525 (1983).

    Google Scholar 

  8. V. B. Vol'eva, T. I. Prokof'eva, I. A. Novikova, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 7, 1632 (1984).

    Google Scholar 

  9. A. Alberti, A. Martelli, A. Hudson, et al., J. Organomet. Chem.,182, 332 (1979).

    Google Scholar 

  10. J. K. Koshi, Adv. Free-Radical Chem.,5, 218 (1975).

    Google Scholar 

  11. A. L. J. Beckwith and K. U. Ingold, Rearrangement in Ground and Excited States, P. De Mayo (ed.), New York-London (1980).

  12. V. V. Ershov, G. A. Nikiforov, A. A. Volod'kin, Sterically Hindered Phenols [in Russian], Khimiya, Moscow (1975).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. I. Prokof'ev, A. S. Masalimov, V. B. Vol'eva, T. I. Prokof'eva, N. N. Bubnov, S. P. Solodovnikov & M. I. Kabachnik

Authors
  1. A. I. Prokof'ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. S. Masalimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. B. Vol'eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. I. Prokof'eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. N. Bubnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. P. Solodovnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. M. I. Kabachnik
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 822–828, April, 1989.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Prokof'ev, A.I., Masalimov, A.S., Vol'eva, V.B. et al. EPR study of photoreduction of adducts of 3,6-di-tert-butyl-o-benzoquinone with dichlorocarbene. Russ Chem Bull 38, 738–743 (1989). https://doi.org/10.1007/BF00953283

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00953283

Keywords

Search

Navigation